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Tag: electrode potential

Cat Links Inorganic chemistry

Using transition metal ions as catalysts

Posted on October 25, 2024October 25, 2024 Sarah Parkes

In the reaction between peroxodisulphate ions and iodide ions, the iodide ions are oxidised to iodine whilst the peroxodisulphate ions

Continue readingUsing transition metal ions as catalysts

Cat Links Inorganic chemistry

Explaining the redox behaviour of transition metals

Posted on October 17, 2024October 23, 2024 Sarah Parkes

Much of the chemistry of transition metal ions is a consequence of the fact that the 3d and 4s orbitals

Continue readingExplaining the redox behaviour of transition metals

Cat Links Calculations, Physical chemistry

Using the Nernst equation to calculate the electrode potential of a half cell

Posted on May 25, 2022October 2, 2024 Sarah Parkes

The standard electrode potential for a half cell means exactly that – everything happening under standard conditions (298K, 100 kPa,

Continue readingUsing the Nernst equation to calculate the electrode potential of a half cell

Cat Links Physical chemistry

The chemistry of fuel cells

Posted on May 24, 2022October 23, 2024 Sarah Parkes

Fuel cells commonly use the reaction between hydrogen and oxygen to produce a voltage, with water being the only waste

Continue readingThe chemistry of fuel cells

Cat Links Physical chemistry

The chemistry of batteries

Posted on May 24, 2022October 23, 2024 Sarah Parkes

Modern storage cells (batteries) can be divided into the non-rechargeable kind (primary cells) and the rechargeable kind (secondary cells). Primary

Continue readingThe chemistry of batteries

Cat Links Calculations, Physical chemistry

Understanding the relationship between the potential difference for an electrochemical cell and Gibbs energy

Posted on May 23, 2022April 24, 2025 Sarah Parkes

The spontaneity or feasibility of a reaction can be described by both a positive Ecell⦵ value or a negative value

Continue readingUnderstanding the relationship between the potential difference for an electrochemical cell and Gibbs energy

Cat Links Physical chemistry

The chemistry of corrosion

Posted on May 23, 2022April 24, 2025 Sarah Parkes

The rusting of iron can be summarised by the equation 4 Fe(s) + 3 O2(g) + H2O(l)  ⇾  2 Fe2O3•xH2O(s)

Continue readingThe chemistry of corrosion

Cat Links Physical chemistry

Predicting the feasibility of redox reactions using standard electrode potentials

Posted on May 19, 2022April 24, 2025 Sarah Parkes

A redox reaction consists of two half reactions – an oxidation and a reduction reaction. If we take a pair

Continue readingPredicting the feasibility of redox reactions using standard electrode potentials

Cat Links Physical chemistry

Determining the potential difference of an electrochemical cell

Posted on May 19, 2022April 24, 2025 Sarah Parkes

We can link any two half cells together to form an electrochemical cell. A high resistance voltmeter prevents current (electrons)

Continue readingDetermining the potential difference of an electrochemical cell

Cat Links Physical chemistry

What is an electrode potential?

Posted on May 18, 2022February 11, 2025 Sarah Parkes

If we place a strip of a metal such as zinc into a beaker containing zinc sulphate (the electrolyte) an

Continue readingWhat is an electrode potential?

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