Empirical vs. molecular formulae

Empirical formula: simplest ratio of the atoms of different elements in a compound

Molecular formula: the actual number of each kind of atom in a molecule of a substance

Ethane, for example, has an empirical formula of CH3 and a molecular formula of C2H6. There are 2 ‘units’ of CH3 in C2H6.

Practice questions

1. Determine the empirical formula of a compound containing 40.0% carbon, 6.6% hydrogen and 53.4% oxygen.

[Tip: assume you have 100g of the compound, in which case 40% = 40g)

2. A mineral was analysed and it was found to contain 12.1% Na, 14.2% Al, 22.1% Si, 42.1% O and 9.48% H2O. What is the formula?

3. A 10.00g sample of a compound contains 3.91g of carbon, 0.87g of hydrogen and the remainder is oxygen. Determine the empirical formula.  

Answers

1. CH2O

2. Na2Al2Si3O10 ï2H2

3. C3H8O3

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